磁场诱导自蔓延高温合成钡铁氧体

Effect of a magnetic field on self-propagating high-temperature synthesis of barium ferrite

  • 摘要: 本文采用外加磁场诱导自蔓延高温合成钡铁氧体,试验用的电磁场强度最高可达1.3T,对无磁场和不同磁场强度下合成的铁氧体的形貌、相组成和磁性能分别进行了表征。研究结果表明:外加磁场对燃烧温度有影响,燃烧温度影响产物转换,燃烧温度较低时,产物为BaFe2O4与BaFe12O19相共存;本试验条件下,磁场强度为0.86T时,合成为M型的钡铁氧体(BaFe12O19),产物结晶完整,有六角片状的钡铁氧体,且性能达到了最佳,矫顽力达到1083(4π)-1·kA·m-1,比剩余磁化强度为16.16 A·m2/kg,比不加磁场条件下分别提高50%和提高32%,说明适当的磁场强度诱导自蔓延高温合成可以改善BaFe12O19的磁性能。

     

    Abstract: Barium ferrite have been made in air by Magnetic field induced self-propagating high-temperature synthesis(SHS),the magnetic field strength individual is o.63T,0.86T and 1.3T.The microstructure,phase composition and magnetic performance of the combustion products were characterized by SEM,XRD and VSM.The results show that a magnetic field causes a significant change in combustion temperature,the products are compound of BaFe2O4 and BaFe12O19 when the combustion temperature are lower.The product is pure BaFe12O19 by SHS when external magnetic field of 0.86T,meanwhile intrinsic coercive force(Hci) and relative remanence(Mr) of the sample increased individually of 50% and 32%,compared that obtained in zero magnetic field,they are 1083(4π)-1·kA·m-1 and 16.16 A·m2/kg.Magnetic performance of BaFe12O19 can be improved magnetic field induced SHS.

     

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