化学气相反应合成MoS2纳米管的研究

Formation of MoS2 nanotubes by chemical vapour deposition

  • 摘要: 以MoO3粉和S为原料,高温下在普通管式炉中化学气相反应制备合成了MoS2纳米管。结果显示制备合成的MoS2纳米管全是开口的,直径分布很均匀,有的纳米管上粘结有纳米粒子。研究了实验温度、气流速度(反应气氛)对实验结果的影响,结果显示反应温度在810~905℃范围内才能生成MoS2纳米管;气流速度(反应气氛)如果不合适将生成MoO2或MoO2-xSx。在实验结果的基础上提出了逐步反应模型和一种新的MoS2纳米管形成机理。

     

    Abstract: MoS2 nanotubes are obtained by the chemical vapour deposition reaction from MoO3 powder and S in a conventional tube furnace at elevated temperature.It is shown that all of MoS2 nanotubes are openended with uniform diameters.Some nanotubes remain attached to nanoparticles.The influences of reaction temperature,argon flow rate(reaction atmosphere) on products are studied.It is shown that nanotubes are prepared only at 810-905℃ with an appropriate argon flow rate.MoO2 or MoO2-xSx is produced while argon flow rate are inaccurate.A stepwise reaction model and a newly growth mechanism of MoS2 nanotubes are proposed based on the experimental results.

     

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