Dy0.15Fe1.85O3磁颗粒的有机改性对其硅油基磁流体磁性能及稳定性的影响

The Effect of Organically Surface Modification of Dy0.15Fe1.85O3 magnetic nanoparticles on Properties and stability of Silicon-oil-based Magnetic Fluid

  • 摘要: 采用共沉淀—相转化法制备出Dy0.15Fe1.85O3纳米磁颗粒,用月桂酸进行了在线有机改性,干燥后用中间体包覆,在超声振荡下将其分散在硅油中,得到硅油基磁流体。研究了月桂酸用量(wt)对磁颗粒性能及中间体用量(wt)对磁流体稳定性的影响。用TEM、XRD对磁颗粒进行表征、用SQUID、VSM对样品的磁性能进行测试。结果表明:在n(Fe2+)/n(Fe3+)/n(Dy3+)=1:2:0.011,反应温度为50℃,月桂酸用量为0.05g/g(磁颗粒),中间体用量为(0.42~0.58)g/g(磁颗粒)的条件下,制得的磁流体具有较强的稳定性和优异的磁性能。

     

    Abstract: Dy0.15Fe1.85O3 magnetic nanoparticles were prepared by coprecipitation method and lauric acid was performed to modify the surface of the magnetic nanopartiples. After claded by intermediate,the product were dispersed in silicon oil under the ultrasonic vibration,the magnetic fluids were obtained. The effect of lauric acid amount on saturation magnetization intensity and intermediate amount on magnetic liquid stability were studied. The properties of magnetic nanoparticles were characterized by transmission electron-microscopy (TEM),X-ray diffraction (XRD),the magnetic properties of magnetic nanoparticles and magnetic fluids were tested by super-conducting quantum magneto meter devices (SQUID) and Vibrating Sample Magnetometer (VSM). The results show that the stability and magnetic properties of the magnetic fluid is best under the condition of lauric acid of 0. 05 g/g,the condition of intermedium of 0. 42~0. 58 g/g,the molar ratio of Fe2+ to Fe3+ to Dy3+ of 1: 2: 0. 011,the reaction of temperatures of 50℃.

     

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