镍酸镧导电薄膜的热处理制度与电性能研究

Properties of LaNiO3 thin films deposited on Si (100) substrates by sol-gel method

  • 摘要: 研究了镍酸镧(分子式LaNiO3,简称LNO)导电薄膜的制备,及其与性能之间的关系。实验结果表明热处理制度和热处理过程中通氧是LNO薄膜获得良好电性能的关键。实验发现LNO薄膜在退火温度550℃时就已经晶化,并且随着退火温度的升高,薄膜电性能也随之提高,但是当温度高于860℃后,LNO薄膜发生了结构相变并伴有NiO的析出,因此导致了薄膜电阻率的升高。较短的预处理时间和较长的退火处理时间有助于薄膜晶粒的长大,从而提高薄膜的电性能。同时也讨论了LNO薄膜电阻率和工作温度的关系。

     

    Abstract: Lanthanum nickel oxide (LaNiO3 or LNO) conducting thin films that could be used as electrodes for improving fatigue and aging properties of ferroelectric thin films were investigated. LNO thin films were directly spin-coated onto Si (100) substrates followed by rapid thermal annealing (RTA) in air and in oxygen, LNO thin films can be crystallized at lower annealing temperature of 550℃, and with the increase in thermal annealing temperature, the LNO thin film owns the lowest electrical resistivity at 750℃. The effects of annealing temperatures and oxygen vacancies on the structure and electrical pro-perties of the films were examined by XRD and four probe measurements, respectively. It is found that with the increase in thermal annealing temperature, the LNO thin film displays a structure transformation above 860℃. Pre-heat treatment temperature and time play a key role to determine the grain size of LNO films. The grain size of LNO film is bigger with shorter pre- heat treatment time and longer annealing time, the film owns a better electrical property. In addition, the relationship between the measured temperature and electrical properties of LNO films is also discussed.

     

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