Gd取代对Ce-Fe-B合金的磁性能以及热稳定性的影响

Effects of Gd substitution on the thermal stability and magnetic properties of Ce-Fe-B ribbons

  • 摘要: Ce基磁体的开发可减少对Pr、Nd等稀土元素的过度消耗, 但是Ce-Fe-B合金居里温度低以及CeFe2相对磁体磁性能的不利影响, 限制了Ce基磁体的实际应用。本文通过Gd取代Ce, 采用熔体快淬方法制备了Ce13-xGdxFe81B6(x = 0.3, 0.7, 1, 4)合金薄带, 并对其相组成、磁性能以及热稳定性进行了研究。结果表明: 不同Gd取代量的Ce13-xGdxFe81B6合金带由2: 14: 1主相、少量CeFe2相和α-Fe组成; 适量Gd取代Ce可提高Ce基磁体的综合性能; 在Gd取代量小于4 at.%时, 合金带矫顽力随Gd取代量增加而增加; 居里温度和合金薄带热稳定性随Gd取代量增加而提高。

     

    Abstract: Ce-based magnets development can reduce the excessive consumption of Pr and Nd elements. The low Curie temperature of Ce-Fe-B alloy and CeFe2 phase disadvantage on the magnetic properties limit the application of Ce-based magnets. In this manuscript, Ce13-xGdxFe81B6(x = 0.3, 0.7, 1, 4)alloy ribbons were prepared by melt quenching method by the substitution of Gd for Ce. The phase composition and magnetic properties were also studied. The results show that the Ce13-xGdxFe81B6 alloy ribbon consists of 2:14:1 main phase, a small amount of CeFe2 phase and α-Fe. The Gd substitution can improve the comprehensive performance. The alloy ribbons coercivity increases with the increase of Gd substitution when substitution of Gd is less than 4 at. %. The Curie temperature and the thermal stability of the alloy ribbon also increase with the increase of Gd substitution.

     

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