Na掺杂对MTG-YBCO临界电流密度特性的影响

EFFECT OF Na ADDITION ON THE Tc,Jc PROPERTIES OF MTG-YBCO

  • 摘要: 本文研究了Na掺杂对MTG -YBCO(YBa2-xNaxCu3 Oy+ 4 0mol%Y2 BaCuO5 ,x =0.0、0.1、0.2 )生长织构及其超导性能的影响。适量Na的掺入有利于MT-YBCO沿 (ab)面的生长 ,改善晶体生长的宏观形貌。同时 ,掺Na后MTG -YBCO试样的Tc ,on变化不大 ,但Tc ,off随掺杂量x的增加而降低 ,即超导转变宽度ΔT增大。适量Na掺杂改善了MTG -YBCO的临界电流密度特性 ,并在临界电流随外磁场变化的曲线中观察到第二峰现象。经 900 ℃高温退火处理后 ,第二峰消失 ,其后的 400 ℃吸氧处理使Jc随吸氧时间增长而增加 ,且第二峰现象重现。本文同时探讨了Na掺杂MTG-YBCO的这种临界电流密度行为形成的机制。

     

    Abstract: The effects of Na addition in the MTG-YBCO (YBa 2-x Na xCu 3O y+40mol% Y 2BaCuO 5) system with x=0.0, 0.1, 0.2 on the texture and superconducting properties have been investigated. It was observed that there is little change on T c,on as x ≤0.2 for these materials, but T c,off decreases with x increase. That is, the larger the Na content in the composition, the broader is the superconducting transition region. With certain Na addition, MTG-YBCO showed an improved critical current density characteristic and a second peak with increasing magnetic field. The post-annealing at 900℃ reduced the critical current density and eliminated the second peak. The followed oxygenation at 400℃ increased the critical current density and recovered the second peak again. These might be connected with the formation of low Tc phase owing to the addition of Na. At the same time, Na doping improved the texture of MTG-YBCO and result in a increase of the crystal growth rate in (ab) plane.

     

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