染料敏化太阳能电池中CuO/TiO2薄膜制备及应用

Application and Application of CuO/TiO2 in Dye-sensitized Solar Cell

  • 摘要: 采用普通直流电沉积和超声直流电沉积制备Cu∕TiO2纳米管阵列∕Ti基复合薄膜,而后在NaOH溶液中用电氧化的方法将Cu单质氧化成CuO,制备了CuO∕TiO2纳米管阵列∕Ti基复合薄膜。利用扫描电子显微镜(SEM)和X射线衍射仪(XRD)对两种复合薄膜电极的形貌和结构进行了表征,详细考察了电镀工艺参数(电流密度)和超声波对复合薄膜形貌的影响。同时通过稳态光电响应技术对复合薄膜电极组成的染料敏华太阳能电池(DSSC)的光电性能进行了研究,结果表明:通过普通直流电沉积在工艺参数(3mA/cm2、5min)处制备的复合薄膜组装的DSSC具有该体系下的最佳光电性能(Jsc=9.00mA/cm2、Voc=0.664V、FF=0.512、η=3.06%);在同等条件下通过超声辅助直流电沉积制备的复合薄膜组装的DSSC的最佳光电性能(Jsc=15.50mA/cm2、Voc=0.688V、FF=0.505、η=5.39%)出现在工艺参数为(6mA/cm2、5min)处。对比可知超声条件下的光电性能较好,且最佳光电性能工艺参数发生了后移。

     

    Abstract: Cu/TiO2 nanotube arrays/Ti-based composite films were fabricated by direct current electro-deposition with or without ultrasound,and then elemental copper will be oxidized to copper oxide by electro-oxidation in NaOH solution.Finally,CuO/TiO2 nanotube arrays/Ti-based composite films were made.The morphology and the structure of CuO/TiO2 nanotube arrays/Ti-based composite films were characterized respectively by means of SEM and XRD.The effects of electroplating process parameters(current density) and ultrasound on the composite films morphology were investigated.At the same time,the optical properties of dye-sensitized solar cells composed of composite film electrode were studied through the steady-state photocurrent technique.The results showed that the dye-sensitized solar cell,composed with composite films prepared in the process parameters(3mA/cm2,5min) without ultrasound aided,exhibits the best performance with the short-circuit photocurrent density(Jsc) 9.00mA/cm2,the open-circuit photovoltage(Voc) 0.664V,fill factors(FF) 0.512,and the photo-current conversion(η) 3.06%;Under the same condition,the dye-sensitized solar cell which was composed with composite films prepared in the process parameters(3mA/cm2,5min) with ultrasound aided,exhibits the best performance with the short-circuit photocurrent density(Jsc) 15.50mA/cm2,the open-circuit photovoltage(Voc) 0.688V,fill factors(FF) 0.505,and the photo-current conversion(η) 5.39%.By contrast,the optical properties of conditions of ultrasound-aided are better than without ultrasound-aided,and the process parameters of the best optical performance moved from 3mA/cm2 to 6mA/cm2.

     

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