磁控溅射法制备锂离子电池硅基薄膜材料研究进展

Progress on Si-based thin films prepared by magnetron sputtering method as anode materials for lithium-ion batteries

  • 摘要: 硅基材料由于具有高理论比容量、低嵌锂电位而有望替代锂离子电池石墨类负极材料,但是首次不可逆容量大、循环寿命差是阻止其商业化的主要问题。薄膜化是提高硅基材料循环寿命的一种有效手段。本文讨论了硅基薄膜在脱嵌锂过程中的结构变化及容量衰减原因,综述了磁控溅射法制备硅基薄膜的研究进展,并对硅基薄膜用于锂离子电池负极材料的研究前景进行展望。

     

    Abstract: Si-based materials are promising alternative anode materials to graphitic carbons for lithium ion batteries(LIBs) due to their high theoretical specific capacity and low potential for lithium insertion.However,the commercialization of Si-based materials has been hindered by the large initial irreversible capacity and poor cycle life.Preparing Si-based thin film materials is an effective way to improve the cycling performance.This article has discussed the change of the crystal structure and surface morphology of the Si thin-film anode during Li insertion and extraction as well as capacity fading.And it summarizes the research progress of Si-based thin films prepared by magnetron sputtering as anode materials for LIBs.Additionally,the future research and development of the Si-based thin films is also presented.

     

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