氢对YFe10V2的结构和磁性的影响

EFFECT OF HYDROGEN ON THE STRUCTURE AND MAGNETIC PROPERTIES OF YFe10V2

  • 摘要: 吸氢使YFe10V2晶格膨胀,磁化强度和居里温度增加,但使Fe-Fe的交换作用系数减小。吸氢不改变铁亚晶格的单易轴磁结构,但使单轴各向异性减弱。氢使各铁晶位的超精细场和同质异能移位都增加。各超晶细参数受氢的影响随温度的降低而减小。磁测量和穆斯堡尔谱的结果表明,在YFe10V2中,钇和钒原子有一与铁亚晶格反平行耦合的磁矩。

     

    Abstract: The lattice of YFe10V2 is expanded by hydrogen. Hydrogen increases both the magnetization and Curie temperature, but decreases Fe-Fe interaction coefficient. Hydrogen does not change the uniaxial anisotropy of YFe10V2 but decreases it obviously. Mossbauer spectra have showed that the hperfine field and isomer shift of each Fe site are increased by hydrogen, and the increment becomes smaller at low temperature, The Mossbauer spectrum results, combining with the magnetization measurement. have proved the existence of the moment of Y and V atom which are antiferromagnetically coupled with Fe moment

     

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