6-乙烯基-1,1-双二茂铁基丁烷的聚合反应及其聚合产物的研究

Studies on polymers of 6-vinyl-1,1-bisferrocenylbutane

摘要: 本文通过单体6-乙烯基-1,1-双二茂铁基丁烷的自由基聚合反应和阳离子聚合反应得到了不同的聚合产物,并利用红外,核磁,XPS,差热热重等方法对其进行了表征和性能鉴定。通过多次自由基聚合反应确定,当反应时间为8小时,反应温度为80℃,AIBN和单体的质量比为0.1时反应效果最佳。

Abstract: In this paper,6-vinyl-1,1-bisferrocenylbutane polymerized under both free radical and cation environment. The polymers were characterized by IR spectrum,1HNMR spectra,XPS,DSC-TG.The best free radical polymerization result was confirmed from the experiments that,when reaction temperature is 80℃,reaction time is 8 hour,AIBN/monomer is 0. 1.