Abstract:
SnS films were prepared by constant current cathodic electrodeposition.Influences of elec-trodeposition parameters,such as the pH of the electrolyte,concentration ratio of Sn
2+ and S
2O
32- ions,and current density,on the composition of the films are investigated.The experiments show that the best electrodeposition conditions for SnS films are pH =2.7,Sn
2+:S
2 O
32- =1:5,
J=3.0mA·cm
-2,
t=1.5h.The film with the composition of Sn
0.995 S
1.005 was prepared,and it was characteriz ed with XRD and SEM.The as-deposited film is polycrystalline with orthorhombic structure and grain sizes of 200-800nm.The transmittan ce and absorption spectrum of the film were measured,and it is found that the transmittance is lower in the spectra of 400-900nm,but it is higher at the wavelengths larger than 1000nm,and the re is an ob vious absorption edge in the vicinity of 950-1000nm.