以陶瓷厚膜为绝缘层的电致发光器件

Electroluminescent device with ceramic thick film as an insulator

  • 摘要: 使用PbMg1/3Nb2/3O3-PbTiO3-PbCd1/2W1/2O3三元系电容器瓷料,采用流延工艺成膜,丝网印刷内电极,低温烧结的方法制备了陶瓷衬底。陶瓷衬底的烧结温度为930~950 ℃。测量了陶瓷厚膜的基本特性,在室温时的相对介电常数εr大于14000,损耗tanδ约为1%,具有极高的品质因素(≥80 μC/cm2)。用SEM技术观察了陶瓷衬底的横断面和陶瓷厚膜表面形貌,内电极连续,厚膜层致密且表面起伏较小,可直接沉积发光层。制备了陶瓷厚膜为绝缘层的ZnS:Mn低压驱动电致发光器件,在50 Hz正弦波驱动下,阈值电压仅为41 V。

     

    Abstract: A novel CIEL device using a sintered multilayer ceramic substrate,consisting of a very high dielectric constant ceramic thick film insulating layer,Ag/Pd alloy in ternal electrodes and a ceramic base was prepared.The composition of the ceramic thick film was PbMg1/3Nb2/3O3(PMN)-PbTiO3(PT)-PbCd1/2W1/2O3(PCW).The ceramic thick film and the internal electrodes were fabricated by casting tape process and silk-screen process,respectively.The ceramic substr ate was fabricated by the green sheet laminating technology and fired at a low sintering temperature,930~950 ℃.The relative dielectric constant and the loss for the ceramic thick film is more than 14000 and about 1% at room temperature.As a insulating layer for the CIEL devices,the figure of merit of the ceramic thick film with a value above 80 μC/cm2,is much higher than that of the ordin ary thin film insulators.Scanning e lectron microscopy (SEM) was used to investigate the morphology of the cross section of the substrate and the surface of the ceramic thick film.The CIEL device with ZnS:Mn as an active layer and Y2O3 as an upper insulator has a low threshold voltage of 41 V under 50 Hz sinusoidal wave voltage driving.

     

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