浸渍-涂布法制备In2O3薄膜

Preparation of In2O3 thin film by dip-coating method

  • 摘要: 以InCl3·4H2O为原料,采用溶胶-凝胶技术、浸渍-涂布法制备了In2O3薄膜。同时对薄膜厚度与In2O3含量、涂布液粘度以及提拉速度等关系进行研究,发现薄膜厚度与涂布液粘度、提拉速度成对数线性关系。膜厚与提拉速度的关系式为tv0.62。XRD、IR测试表明经过400℃煅烧,PVA已经完全排除。SEM照片表明薄膜形貌平整、光亮,从而为该种材料制作实用的气敏元件打下了良好的基础。

     

    Abstract: The In2O3 thin films were prepared on glass substrates by sol-gel technique and dip-coating of an aqueous In(OH)3 gel prepared from InCl3·4H2O and PVA, followed by drying at 110℃ and calcinating at 400℃. The relationships between the thickness of In2O3 thin films and In2O3 content, viscosity of the dipping solution and raising rate were investigated. It is found that there are well logarithmic-linear relationships between film’s thickness and viscosity of the dipping solution, raising rate. The thickness(t)of In2O3 thin films and the raising rates(v) of substrates from dipping solutions are correlated with an expression of tv0.62. The results obtained from XRD and IR show that PVA is completely removed after calcination at 400℃. SEM photographs show the morphologies of the thin films are flat and bright, so that it is possible to prepare practical In2O3 gas sensor by using this film.

     

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