Abstract: A study of fluoresence spectra and photoconducting properties of C₆₀-toluene derivation/diamond-like (DL) carbon films was reported. The fluorescence spectra show that C₆₀-toluene derivation exhibits photoluminscence (PL) near 460 nm at room temperature in contrast to pure C₆₀. But the PL intensity decreases after doping with I₂. The photoconductivity of the films doped with I₂ increases by one order of magnitude. The photoconducting intensity of the C₆₀-toluene derivation/DL carbon films would be dropped a little as compared with pure C₆₀-toluene derivation. The DL carbon film can be used as a passivation film.