Pechini溶胶-凝胶法制备SiO2/TiO2复合微粒

Preparation of SiO2/TiO2 composite particles by Pechini sol-gel method

  • 摘要: 采用超声Stöber法制备了单分散性的纳米载体SiO2,再采用Pechini溶胶-凝胶制备法制备出SiO2/TiO2复合微球。通过X射线衍射仪、场发射扫描电子显微镜(FESEM)对粉体的晶型和显微形貌进行测试分析。结果表明:纳米载体SiO2球形颗粒为无定形态,TiO2粉体为形貌多样的块状颗粒,大颗粒粒径大于10μm;Ti/Si(摩尔比)的变化明显影响合成复合粉体的形貌和粒径,当Ti/Si=1:3时可获得球形复合微球,且不存在块状颗粒。

     

    Abstract: Monodisperse SiO2 particles were synthesized by Stöber method using ultrasound field.The SiO2/TiO2 core-shell particles were prepared by Pechini sol-gel method.The crystal phases and micromorphology were characterized by X-ray diffraction(XRD) and Scanning electron microscope(SEM).The results show that the SiO2 particles are monodisperse non-crystalline solid particles about 300nm.The SEM images of TiO2 powders show wide distribution of TiO2 particles having varied shape.And the large TiO2 particles are larger than 10μm.The micromorphology of SiO2/TiO2 particles changes significantly with the increment of Ti/Si(mol/mol).SiO2/TiO2 core-shell particles could be obtained when Ti/Si=1:3.

     

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