常压镍氧化物超导薄膜研究进展与展望

Research progress and prospect of ambient-pressure nickelate superconducting thin films

  • 摘要: 本文综述了常压环境下镍氧化物超导薄膜的研究进展,重点探讨无限层结构与双层Ruddlesden-Popper结构镍氧化物的材料制备、性能调控及机理探索。系统分析了脉冲激光沉积、氧化物分子束外延以及强氧化原子逐层外延等关键生长技术的特点与适用范围。研究表明,通过多元掺杂与应变调控,无限层镍氧化物的超导转变温度已提升至近40 K;双层结构镍氧化物薄膜在常压下实现了起始温度超过40 K的超导转变,并呈现出零电阻和完全抗磁性,表现出典型的非常规超导相图特征。最后,对镍氧化物超导薄膜的进一步发展,包括制备技术优化、新材料体系探索以及微观配对机制的阐明,进行了简要总结与展望。

     

    Abstract: This review summarizes recent advances in the study of nickelate superconducting thin films under ambient pressure, with a focus on material synthesis, property modulation, and mechanistic investigation of infinite-layer and bilayer Ruddlesden-Popper (RP) phase nickelates. We systematically analyze the characteristics and applicability of key fabrication techniques, including pulsed laser deposition (PLD), oxide molecular beam epitaxy (OMBE), and gigantic-oxidative atomic-layer-by-layer epitaxy (GOALL-Epitaxy). Research demonstrates that through multi-element doping and strain engineering, the superconducting transition temperature (Tc) of infinite-layer nickelates has been enhanced to nearly 40 K. Moreover, bilayer RP nickelate thin films have achieved superconducting transitions with onset temperatures exceeding 40 K at ambient pressure, exhibiting zero resistance, complete diamagnetism, and unconventional superconducting phase diagrams. Finally, we provide a concise summary and outlook regarding the further development of nickelate thin film fabrication technologies, the discovery of novel material systems, and the elucidation of their microscopic pairing mechanisms.

     

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