基于二氧化锰负载细菌纤维素的复合多孔超级电容器电极的制备

Preparation of MnO2/BC porous electrode for supercapacitors

  • 摘要: 本文采用一步水热法,以细菌纤维素气凝胶(BC)为载体制备了二氧化锰/细菌纤维素气凝胶复合材料,期望获得具有高比电容,稳定性好的三维多孔复合电极材料。通过扫描电镜(SEM)和广角X射线衍射(WAXD)的方法对制备的二氧化锰/细菌纤维素气凝胶复合材料进行形貌和结构表征,结果显示二氧化锰和细菌纤维素的质量比为1.8:1时,在细菌纤维素表面均匀的覆盖了花瓣状的二氧化锰,二氧化锰的晶型为δ晶型。电化学测试结果表明,在1 M KOH电解液中,复合材料的比电容在1~50 mV s-1扫速下,随着扫速的增加而呈现降低的趋势;在电流密度为0.25 A g-1时,质量比为1.8:1时,复合材料比电容量最高,达到210F g-1;多次循环稳定性结果表明,制备的复合材料具有良好的循环性,在扫速为1 mV s-1下经过1000次循环伏安测试后,比电容保持率为86.8%。本文所阐述的二氧化锰负载细菌纤维素多孔气凝胶的研究为快速开发三维多孔结构的复合电极材料提供了重要的借鉴意义。

     

    Abstract: In this paper, manganese dioxide/bacterial cellulose aerogel compositeswere prepared via one-step hydrothermal method using bacterial cellulose aerogel as matrix, aiming to obtain 3 D porous electrode with high specific capacitance and good stability. Morphology and crystal form of MnO2/BC aerogel compositewere characterized by SEM and WAXD., Petal-shaped manganese dioxide is uniformly covered on the surface of the bacterial cellulose at a mass ratio of anganese dioxide to bacterial cellulose as 1.8:1.WAXD results indicate that δ-crystal of MnO2 is successfully grown on the surface of the bacterial cellulose. The electrochemical testing results show that the specific capacitance of the composite material decreases with the increase of the scanning speed at the rate of 1 to 50 mV s-1 in the 1 M KOH solution. MnO2/BC aerogel composite exhibit an excellent specific capacitance is up to 210 F g-1 at current density of 0.25 A g-1 and the mass ratio is 1.8:1.. After 1000 cyclic volt-ampere tests at scan rate of 1 mV s-1,the specific capacitance retention rate is 86.8%, showing outstanding cycling properties of MnO2/BC aerogel composite.

     

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