Abstract: The stimulated Brillium Scattering of InGaAsP/InP heterostructure bulk materials in testing the near-infrared photoluminescence has been first reported. It showed as a matter of experience that as the temperature of the tested material is the rang of 20K to 150K, and the input optical power is 4.5 mW to 6.0 mW, the symmetrical in frequency-drift and in optical power, multiple-phonon accompanied rays in the photoluminescence spectrum may be observed.