改性TiO2在各种室内环境净气领域的研究综述

A review of the research on modified TiO2 in indoor air purification

  • 摘要: 随着现代建筑密闭性增强及装修材料的广泛使用,室内空气质量已成为影响人体健康的关键环境因素。TiO2(二氧化钛)光催化技术因其环境友好、高效稳定等特性,被认为是解决各类室内空气净化问题最具前景的技术之一。然而,纯TiO2禁带宽度较大(约3.2 eV),仅能利用紫外光(<387 nm),且光生电子-空穴对的高复合率严重制约其实际应用性能。本文综述了改性TiO2在室内空气净化领域的最新研究进展,通过掺杂、构建异质结、引入氧空位等改性策略,从多方面提升材料性能,以拓宽光响应范围至可见光区、降低载流子复合率、提高活性物种生成效率,从而加速其向实际应用的转化。尽管如此,目前改性TiO2及其复合材料大多仍处于实验室研究阶段,距离市场化应用尚有较大差距。

     

    Abstract: With the increasing enclosure of modern buildings and the widespread use of decorative materials, indoor air quality has become a critical environmental factor affecting human health. TiO2 (titanium dioxide) photocatalytic technology is regarded as one of the most promising approaches for addressing diverse indoor air purification challenges owing to its environmental compatibility, high efficiency, and stability. However, the wide bandgap (approximately 3.2 eV) of pure TiO2 restricts its photoactivity to ultraviolet light (<387 nm), and the rapid recombination of photogenerated electron-hole pairs significantly hinders its practical performance. This article reviews recent advances in modified TiO2 for indoor air purification. Through modification strategies-including metal and non-metal doping, heterojunction construction, and oxygen vacancy introduction-the material's fundamental properties are enhanced across multiple dimensions: the optical response is extended into the visible-light region, charge carrier recombination is suppressed, and the generation efficiency of reactive species is improved, thereby accelerating the transition toward real-world applications. Nevertheless, most modified TiO2 materials and their composites remain at the laboratory research stage, and a considerable gap persists before commercial deployment.

     

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