钙钛矿薄膜光致发光在线检测系统及其光处理发光增强研究

Enhanced photoluminescence and online detection system of perovskite thin films by light treatment

  • 摘要: 溶液法制备的钙钛矿薄膜内部存在大量缺陷,这些缺陷作为非辐射复合中心显著降低了其光致发光性能。光处理是一种有效钝化钙钛矿薄膜内部缺陷的方法,但其钝化效果受处理时间的影响。本文设计并搭建了一套光处理与同步光致发光检测装置,将光致发光的激发光源同时用作光处理光源,实现了原位实时检测光处理过程中钙钛矿薄膜的光致发光变化。利用该系统,研究了光处理时间对钙钛矿薄膜光致发光特性的影响。结果表明,随着光处理时间的增加,光致发光峰值强度逐渐增强并最终趋于稳定,从而确定了最佳光处理时间。经光处理后,钙钛矿薄膜的光致发光强度提升了6倍以上。基于上述研究,可在钙钛矿薄膜光处理设备中引入光致发光在线监测模块,以优化和监控光处理对钙钛矿薄膜质量的改善效果。

     

    Abstract: Perovskite thin films fabricated through the solution process exhibit a significant number of internal defects. These defects serve as nonradiative recombination centers, markedly reducing photoluminescence intensity. While light treatment offers a promising method for passivating such intrinsic defects, the effectiveness of passivation is highly dependent on the duration of illumination. A photoluminescence detection system has been developed for the in-situ measurement of photoluminescence in perovskite films during light treatment. In this system, the excitation light source for photoluminescence also functions as the light treatment source. Utilizing this setup, the impact of varying light treatment durations on the photoluminescence of perovskite films is investigated. The findings indicate that as the light treatment duration increases, the peak intensity of photoluminescence progressively rises and eventually reaches a plateau. An optimal light treatment duration is identified. Following light treatment, the photoluminescence intensity of the perovskite films is amplified by more than sixfold.

     

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