常压镍氧化物超导薄膜研究进展与展望

Research progress and prospect of ambient-pressure nickelate superconducting thin films

  • 摘要: 镍氧化物超导体是继铜基超导体和铁基超导体之后的第三大非常规高温超导家族,近年来一直是超导材料和物理领域内的研究热点。其中,常压下的镍氧化物超导薄膜因其在物理研究和未来潜在应用中的便利性受到人们的重点关注。本文对常压环境下镍氧化物超导薄膜的研究进展进行综述,重点探讨无限层结构与双层Ruddlesden-Popper结构镍氧化物的薄膜制备、性能调控及机理探索,系统分析脉冲激光沉积、氧化物分子束外延以及强氧化原子逐层外延等关键薄膜生长技术的特点与适用范围。研究表明:通过多元掺杂与应变调控,无限层镍氧化物薄膜的超导转变温度已被提升至近40 K;双层结构镍氧化物薄膜在常压下实现了起始温度超过60 K的超导转变,并呈现出零电阻和完全抗磁性,表现出典型的非常规超导相图特征。对镍氧化物超导薄膜在制备技术优化、新材料体系探索以及微观配对机制的阐明等方面发展前景进行了展望。

     

    Abstract: Nickelate superconductors constitute the third unconventional high-temperature superconducting family after copper-based superconductors and iron-based superconductors, and have been a research hotspot in the fields of superconducting materials and physics in recent years. Among them, ambient-pressure nickelate superconducting thin films have attracted significant attention due to their convenience in physical research and potential future applications. This review summarizes recent advances in the study of nickelate superconducting thin films under ambient pressure, with a focus on film synthesis, property modulation, and mechanistic investigation of infinite-layer and bilayer Ruddlesden-Popper (RP) phase nickelates. We systematically analyze the characteristics and applicability of key fabrication techniques, including pulsed laser deposition (PLD), oxide molecular beam epitaxy (OMBE), and gigantic-oxidative atomic-layer-by-layer epitaxy (GOALL-Epitaxy). The research results demonstrate that through multi-element doping and strain engineering, the superconducting transition temperature of infinite-layer nickelate film has been enhanced to nearly 40 K. Moreover, bilayer RP nickelate thin films have achieved superconducting transitions with onset temperatures exceeding 60 K at ambient pressure, exhibiting zero resistance, complete diamagnetism, and unconventional superconducting phase diagrams. We provide a outlook regarding the further development of nickelate thin film fabrication technologies, the discovery of novel material systems, and the elucidation of their microscopic pairing mechanisms.

     

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