锂离子电池预锂化技术研究进展

Research progress on prelithiation technology for lithium-ion batteries

  • 摘要: 锂离子电池在首次充电过程中,负极-电解质界面处固体电解质界面膜(SEI膜)的形成以及循环过程中不可逆副反应的发生会消耗活性锂,导致不可逆容量损失,甚至引发电极体积变化与结构坍塌,这已成为制约长寿命电池性能的关键因素。通过预锂化技术补充活性锂是提升电池性能的重要途径。本文系统探讨了适用于不同电极结构(尤其是硅基、锡基等高比容量合金类负极)的各类预锂化方法及其作用机理,分析了电解质预锂化、隔膜预锂化及粘结剂预锂化技术的优缺点,评估了各策略在提升初始容量、改善循环稳定性、增强工艺兼容性以及减少潜在副作用方面的有效性,总结了当前面临的主要挑战,并提出了针对性的解决思路与发展方向,以期为预锂化技术的进一步发展及规模化应用提供参考。

     

    Abstract: The formation of a solid electrolyte interphase (SEI) film at the anode-electrolyte interface during the first charge process, along with irreversible side reactions in subsequent cycles, consumes active lithium, resulting in irreversible capacity loss. This phenomenon has become a primary factor restricting the performance of long-cycle-life batteries. It may also induce electrode volume changes and structural collapse. Supplementing active lithium through prelithiation technology is an important approach to enhance battery performance. This paper systematically explores various prelithiation methods tailored to different electrode structures (particularly specific electrode types) and their underlying mechanisms. Furthermore, it discusses the importance of developing effective electrolyte, separator, and binder prelithiation technologies. The effectiveness of each strategy is evaluated in terms of improving initial capacity, enhancing cycle stability, resolving compatibility issues, and minimizing potential side effects. Additionally, the paper analyzes current challenges and provides an outlook on future development, aiming to offer references for the advancement and large-scale application of prelithiation technology.

     

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