烧结工艺对多层陶瓷电容式滤波器表面孔洞及微观形貌的影响

Effect of sintering process on surface holes and microscopic morphology of multi-layer ceramic capacitive filters

  • 摘要: 本文系统分析了烧结曲线、烧结匣钵及埋粉烧结对多层陶瓷电容式滤波器表面孔洞及微观形貌的影响规律,深入研究了BaTiO3基陶瓷材料的烧结机理。工艺实验结果表明:优化烧结曲线可以提高滤波器的烧结致密性;使用涂层匣钵和预制粉埋烧可以解决瓷体表面孔洞问题。通过优化烧结温度、保温时间和升温速率,提高了瓷体强度及致密性;在基体陶瓷材料制浆后,通过制作匣钵涂层来隔绝产品与匣钵之间的接触,阻止了蓝色CoAl2O4尖晶石杂质的生成;使用基体材料造粒后制备预制粉用于埋烧,为滤波器烧结提供了低的氧分压气氛,加快了烧结初期的致密化进程,促使烧结初期形成的气孔转移至晶界,利于后期排出。本研究解决了滤波器烧结表面孔洞的问题,为解决电子元器件烧结过程中的类似不良问题提供了有价值的参考。

     

    Abstract: In this paper, the influences of sintering curves, sintered saggar and buried power sintering on the surface holes and micro-morphology of multi-layer ceramic capacitive filters are systematically analyzed, and the sintering mechanism of BaTiO3 based ceramic material was deeply researched. The results of process experiments reveal that the sintering densification of the filter can be improved by optimizing the sintering curve. Meanwhile, the problem of surface holes can be solved by using coated saggar and prefabrication powder buried firing. By optimizing the sintering temperature, holding time and heating rate, the strength and densification of the porcelain body were improved. The coated saggar is made of the base ceramic material after pulping to isolate the contact between the product and saggar, preventing the formation of bule CoAl2O4 spinel impurities. The prefabricated powder is prepared by the matrix material after granulation for buried firing, which provides a low oxygen partial pressure atmosphere for the filter sintering, and speed up the densification process in the initial sintering stage, so that the pores in the initial sintering stage are transferred to the grain boundary. This is conducive to later discharge. The presnet work solved the problem of holes on the surface of porcelain body, which can provide some valuable references for solving the similar problems in the sintering process of electronic components.

     

/

返回文章
返回