晶界添加氢化镝制备耐高温烧结钕铁硼的研究

Preparation of high temperature resistant sintered neodymium iron boron magnet by adding dysprosium hydride DyHx at grain boundaries

  • 摘要: 为了将晶界添加氢化镝DyHx制备耐高温烧结钕铁硼应用于生产实践, 本文对比了在无镝基材中分别通过熔炼添加、晶界添加0.5wt.%的Dy所制备得到磁体的磁性能、热稳定性, 对晶界添加磁体的均匀性进行了验证分析, 对晶界添加DyHx提升矫顽力Hcj和热稳定性的机理进行了研究。结果表明: 室温20 ℃下, 晶界添加相比熔炼添加的磁体其Hcj提高0.32 kOe, Br提高0.09 kGs, 热损降低21%以上; 晶界添加磁体的剩磁Br的均匀性、不可逆磁通损失Hirr的均匀性均与单合金熔炼工艺无差别; 晶界添加磁体矫顽力以及热稳定性的提升主要归因于Dy元素直接利用率的提高和硬磁的(Nd, Dy)-Fe-B壳层的形成。

     

    Abstract: In order to apply the method of adding DyHx at grain boundaries to produce high temperature resistance sintered NdFeB magnet on the production line, this work compared the magnetic properties and thermal stability of magnets prepared by melting adding and grain boundaries adding the same amount of 0.5wt.% Dy at a dysprosium-free substrates, and analyzed the uniformity of the DyHx grain boundaries added magnet.The mechanism of the increase of Hcj and the improvement of thermal stability by adding DyHx to grain boundary was also studied.The results show that when at room temperature of 20 ℃and compared with the melting adding magnet, the grain boundaries adding magnet has a Hcj increased of 0.32 kOe and Br increased of 0.09 kGs, and the Hirr decreased more than 21%.The uniformity of the grain boundaries adding magnet is the same as the single alloy melting processes magnet when consider the standard deviation of residual magnetic Br and irreversible magnetic flux loss Hirr.The improvement of coercive force Hcj and thermal stability of the grain boundaries adding magnets is mainly attributed to the increase of the direct utilization rate of Dy elements and the formation of hard magnetic (Nd, Dy)-Fe-B shells.

     

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