Fe3+对钛酸锶稀薄燃烧氧敏薄膜电阻的影响

Effect of Fe3+ addition on resistance of SrTiO3 thin film as oxygen sensor

  • 摘要: 利用溶胶-凝胶的方法制备钛酸锶氧敏薄膜,掺杂不同含量的铁离子,并测试了不同氧分压、温度下薄膜的电阻。发现铁离子的含量在20mol%~25mol%之间时,掺杂对钛酸锶电阻的降低有明显的影响,含铁在20%和25%的钛酸锶在600~800℃之间电阻的变化趋近为零,铁的含量大于25%或小于20%薄膜没有出现这种现象。

     

    Abstract: The SrTiO3 thin film used as oxygen sensor was prepared by Sol-gel method. The Fe ion content in Fe-doped SrTiO3 thin film is 10mol%, 15mol%, 20mol%, 25mol%, 30mol%, respec-tively. All samples were measured in the temperature range of 600℃-800℃ and PO2 region from 0 to 0.25× 105Pa.The results show that the thin film exhibit P-type conduction. It is found that when the Fe ion content is between 20mol% to 25mol%,the resistance of SrTiO3 fells obviously and it is independent on temperature from 600℃ to 800℃.The results can be explained according to the defect chemistry equations.

     

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